Page 71 - 《橡塑技术与装备》2023年3期

理论与研究 豆鹏飞·聚苯乙烯 / 聚苯胺核壳型复合材料的合成表征研究

2009, 63-66. [J]. 宇航材料工艺，1989, 4(5):24-28.
[11] 周震涛，刘芳，杨洪业 . 聚苯胺合成中的放大与研究 [J]. 华东 [23] 朱雯，黄芳婷，董观秀 . 无皂乳液聚合法制备单分散聚苯乙烯
理工大学学报，1997, 25(10):25-60. 微球 [J]. 功能材料，2012, 6(43):775-776.
[12] 冯晓苗 , 石乃恩 . 具有高电活性的聚苯乙烯 / 聚苯胺核壳材料 [24] 陆威，王姗姗，等 . 苯乙烯的悬浮聚合及聚苯乙烯磺化 [J]. 现
的制备 [J]. 南京邮电大学学报 ( 自然科学版， 2008, 28(1): 1-2. 在塑料加工应用，2005, 17(4):1-2.
[13] 潘祖仁 . 高分子化学（第五版）[M]. 北京 ：化学工业出版社， [25] 孙红绢，胡傲厚，等 . pH 值对聚苯胺的结构和导电性能的影
2011:72-74. 响 [J]. 西南科技大学学报，2011, 26(1):1-3.
[14] 周益明，忻新泉 . 低热固相合成化学 [J]. 无机化学学报， [26] 曹同玉 . 聚合物乳液合成原理、性能及应用 [M]. 北京 : 化学
1999, 15(3): 273-292. 工业出版社，1997:33-34.
[15] 雷立旭，忻新泉 . 室温固相化学反应与固体结构 [J]. 化学通报， [27] SHR TCHCOOK H, AVNIR D. Submicron silica/polystyrene
1997, 15(2):1-7. composite particles prepared by a one - step sol - gel
[16] Jiaxing Huan, James A. More, et al. Mechanchemical Route process[J]. Chem Mater, 2003. 15(8):1 690-1 694.
to the Conducting Polymer Polyainline. Macromolecules, [28] NEOH K G , PUN M Y, KANG E T, et al. Polyaniline treated
2005, 38: 317-321. with organic acids doping characteristics and stability[J].
[17] Jian Gong, Xiu-Jun Cui, Zhong-Wei Xie, et al. The solid- Synth Met, 1995, 73(7):29-215.
state synthesis of polyaniline /H4SiW 12 O 4 0 materials. [29] HUANGK,WANMX.Self-assembled polyaniline
Synthetic Metals, 2002, 129: 187-192. nanostructures with photoisomerization function[J].Chem
[18] 吐尔逊 · 阿布都热依木，张校刚 . β- 萘磺酸掺杂聚苯胺纳米 Mater, 2002, 14(8):3 462-3 492.
粒子的固相反应制备及其表征 [J]. 高分子化学学报，2003, [30] MCCRTHTH PA, HUANG J, YANG SC, et al. Synthesis
2(6): 858-861. and characterization of water-soluble chiral conducting
[19] 吐尔逊 · 阿布都热依木 , 张校刚 . 固相反应法制备樟脑磺酸掺 polymers [J]. 2002, 18(1):259-263.
杂聚苯胺 [J]. 应用化学 , 2003, 20(11):1 009-1 101 [31] Wang L Y, Lin Y J, Chiu W Y. Synthesis and properties of
[20] 程登余 . 导电高分子聚苯胺合成和应用研究 [J]. 贵州大学学 monodisperse conductive core-shell latexes [J]. Synth Met,
报，2009, 4(9):1-2. 2001, 119(1):155-156.
[21] 宋月贤，韦玮，郑元锁 . 用于电磁屏蔽与吸波技术的聚苯胺导 [32] 武克忠，王庆飞，马子川，等 . 循环伏安法电化学合成聚苯胺
电聚合物的研究进展 [J]. 化工新型材料 , 2000, 28(9):5-10. [J]. 绍兴文理学院学报，2011, 30(8):2-4.
[22] 万梅香，李军朝，李素珍 . 导电高聚物的微波吸收机理的研究

Synthesis and characterization of polystyrene/polyaniline
core-shell composite

Dou Pengfei

(Changqing Oil Field Co. LTD., Yulin 718100, Shaanxi, China)
Abstract: Polystyrene microspheres were synthesized by soap free lotion polymerization. Polystyrene
microspheres were sulfonated with concentrated sulfuric acid, and sulfonic groups were introduced to
improve the adsorption capacity of polystyrene microspheres for aniline. Polystyrene/polyaniline core-shell
composite was prepared by chemical oxidation. The morphology and composition of polystyrene/polyaniline
core-shell composite were characterized by field emission scanning electron microscopy, transmission
electron microscopy and infrared spectroscopy. At the same time, the electrochemical performance of the
composite was characterized by electrochemical workstation. The results show that the particle size of the
composite is 190~230 nm, and it has good electrochemical activity.
Key words: polystyrene microspheres; chemical oxidation; compound material; Electrochemical activity
(R-03)

年
2023 第 49 卷 ·23·