Page 53 - 2019-6

材料与应用 康永 等·界面聚合法聚氨酯微胶囊相变材料性能研究

L，Delobel R.Microencapsulation of phosphate:application Energy, 2011,85(9):2 061~2 071.
to flame retardedcoated cotton[J].Polymer Degradation and [14] 李伟，张兴祥，由明 . 悬浮聚合法制备相变材料微 / 纳胶囊 [J].
Stability，2002 (77):285~382. 高分子材料科学与工程，2010,(2):36~39.
[3] ALAY S，ALKAN C，GODE F.Steady-state thermal comfort [15] 李建立，薛平，韩晋民，等 . 微胶囊化相变材料的制备与评价
properties of fabrics incorporated with microencapsulated 方法 [J]. 精细化工，2007,24(9):843~847.
phase change materials [J].Journal of The Textile Institute， [16] 宋德清 . 相变微胶囊的制备和影响因素研究 [D]. 广州 ：华南
2012,103(7):757~765. 理工大学，2009.
[4] LI L，LIU S，HUA T，et al.Characteristics of weaving [17] 高明珠 . 相变材料微胶囊在纺织服装中的应用 [J]. 四川纺织科
parameters in microcapsule fabrics and their influence 技，2004,(2):34~36.
on loading capability[J].Tetile Research Journal ， [18] 由明 . 含相变材料微胶囊的聚氨酯泡沫制备及性能 [D]. 天津 ：
2012,83(2):113~121. 天津工业大学，2007.
[5] 张寅平，胡汉平，孔祥冬，等 . 相变贮能：理论和应用 [M]. 合肥： [19] 张萍丽，刘静伟 . 相变材料在纺织服装中的应用 [J]. 上海纺织
中国科学技术大学出版社，1996. 科技，2002,30(5):47~48.
[6] 闫玉宵，沈兰萍 . 微胶囊缓释性理论研究及影响因素的分析 [J]. [20] 宋肇棠 . 调温纤维及其纺织品 [J]. 印染助剂，2004,21(3):1~4.
北京纺织，2002,23(5):47~52. [21] 张冬霞，郭凤芝 . 相变材料在调温服装中的应用 [J]. 针织工业，
[7] 苏小燕 . 相变材料微胶囊在纺织品中的研究发展 [J]. 现代纺织 2007,(03):28~31.
技术，2011,25(11):54~56. [22] 司琴，林鹤鸣，杨雷，等 . 相变纳米胶囊及其在纺织品上的应
[8] 闫飞，陆大年 . 织物整理用相变微胶囊的制备 [J]. 印染助剂， 用 [J]. 浙江理工大学学报，2009,26(4):495~500.
2011,35(1):32~34. [23] 曹虹霞，李和玉，张健飞 . 相变材料微胶囊的制备及应用 [J].
[9] A.Nejman，B.Heat balance of textile materials modified 天津工业大学学报，2011,30(1):12~15.
with the mixtures of PCM microcapsules，Thermochim[J]. [24] 刘晓庚，谢亚桐 . 微胶囊制备方法的比较 [J]. 粮食与食品工业，
Thermochimica Acta, 2013，569(18):144~150. 2005,(1):28~31.
[10] P.Monllor ， L.Sánchez ， F.Cases.Thermal Behavior of [25] H Wa ng, L Z ha o ， G So ng.Orga ni c -i norga ni c hybri d
Microencapsulated Fragrances on Cotton Fabrics[J].Textile shell microencapsulated phase change materials
Research Journal, 2009,79(4):365-380. prepared from SiO2/TiC-stabilized pickering emulsion
[11] K.Choi ， C.Cho ， P.Kim .The rm a l st ora ge / rel e a se a nd polymerization[J].Solar Ener gy Materials & Solar
mechanical properties of phase change materials on poliester Cells, 2018, 175(26):102~110.
fabrics[J].Textile Research Journal, 2004,74(4):292~296. [26] EM Languri, HB Rokni, J Alvarado.Heat transfer analysis
[12] G.Nelson.Application of microencapsulation in textiles[J]. of microencapsulated phase change material slurry flow in
International Journal of Pharmaceutics, 2002,242(1):55~62. heated helical coils:A numerical and analytical study[J].
[13] A.Sari，A.Bicer，Ö.Lafci，M.Galactitol hexa stearate International Journal of Heat & Mass Transfer, 2018 , 118(5
and galactitol hexa palmitate as novel solid–liquid phase 6):872~878.
change materials for thermal energy storage[J].Solar

Study on properties of polyurethane microencapsulated phase
change materials by interface polymerization

Kang Yong
(Yulin Hanting Chemical Technology Development Co. LTD., Yulin 718100, Shaanxi, China)

Abstract: Polyurethane microcapsule phase change materials were prepared by interfacial
polymerization using stearic butyrate as core material, styrene-maleic anhydride copolymer (SMA) as
emulsifier, toluene 2,4-diisocyanate (TDI), isophorone diisocyanate (IPDI), polyether polyol (molecular weight
500 and 1000) as reactive monomers. The surface morphology, thermal stability and chemical structure of
the microcapsules were characterized and analyzed by optical microscopy and weighing method. The
microcapsules of phase change materials were treated on the surface of fabrics by dip-rolling method to
realize the function of heat storage and temperature regulation of textiles. The surface morphology and
finishing effect of the microcapsules were tested by optical microscopy and thermometer. The experimental
results showed that the stability of microcapsules prepared by TDI and polyether polyol (molecular weight
500) monomer and the effect of finishing on fabrics were obviously better; The effect of microcapsules

2019 第 45 卷 ·37·
年