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橡塑技术与装备（橡胶） CHINA RUBBER/PLASTICS TECHNOLOGY AND EQUIPMENT (RUBBER)
拉伸强度和扯断伸长率基本不变 ；老化过程中，拉伸 [2] Nair A B, Kurian P, Joseph R. Ethylene–propylene–diene
terpolymer/hexa fluoropropylene–vinylidinefluoride
强度先变小后变大，扯断伸长率急剧变小，50% 定伸
dipolymer rubber blends : Thermal and mechanical
应力略微增大。 properties[J]. Materials & Design, 2012, 36:767~778.
（5）综合来说，DCP/ 双酚 AF 硫化体系下， [3] VanderAar.C.P.J, 黄汉生 . 利用水溶性聚合物使三元乙丙橡胶
和氟橡胶与金属黏合 [J]. 有机氟工业，1999(4):54~60.
EPDM/FKM 共混胶在老化过程中拉伸强度和扯断伸
[4] Dutta S, De P P, De S K. Ionic elastomer blends of zinc salts
长率变化均较大，50% 定伸应力变化较小，不利于提
of maleated EPDM rubber and carboxylated nitrile rubber[J].
高 EPDM 共混胶的耐老化性能。 Journal of Applied Polymer Science, 2015, 69(1):153~160.
[5] 殷俊，陈朝霞，艾书伦，等 . 三元乙丙橡胶共混改性的研究进
展 [J]. 合成橡胶工业，2015, 38(3):244~248.
参考文献 ： [6]
[1] 李剑，田明，包志方，等 . 耐高温耐老化龟裂氟橡胶 / 三 王鹤，丁莹，赵树高 . 三元乙丙橡胶的分子结构参数对其性能
的影响 [J]. 合成橡胶工业，2014, 37(2):139~143.
元乙丙橡胶并用胶的制备与性能研究 [J]. 橡胶工业，2015,
62(11):651~655.
Effect of DCP/bisphenol AF vulcanization system and amount on the
aging resistance of EPDM/FKM blended rubber
Zhang Zuoxin, Xue Bin, Deng Tao
(Qingdao University of Science and Technology, Qingdao 266042, Shandong, China)
Abstract: Effect of DCP/bisphenol AF vulcanization system and amount on the aging resistance of EPDM/
FKM blended rubber were studied. Tth research has shown that with the increase of vulcanizing agent DCP
amount, the vulcanization degree of EPDM/FKM blended rubber becomes longer, and the curing time of the
process becomes shorter. Before aging, the tensile strength of the blended rubber becomes larger, and the
elongation at break first turn larger and then turn smaller, and the tensile stress at 50% becomes larger; During
the aging process, the tensile strength first becomes smaller and then becomes larger, the elongation at
break is sharply smaller, and the tensile stress at 50% is slightly increased. As the amount of vulcanizing agent
bisphenol AF becomes larger, the degree of vulcanization is substantially unchanged, and the process curing
time becomes shorter; Before aging, the tensile strength and elongation at break of the blending rubber are
basically unchanged; during the aging process, the tensile strength first becomes smaller and then becomes
larger, the elongation at break is sharply smaller, and the tensile stress at 50% is increased slightly.
Key words: DCP; bisphenol AF; EPDM/FKM blended rubber; aging resistance
(R-12)
杜邦携手埃克森美孚开发出新产品
DuPont teamed up with ExxonMobil to develop new products
据外媒报道，杜邦运输与工业公司宣布，与埃克森美孚化学公司在弹性体方面的合作取得巨大成功。
他们联手开发出用于汽车转角成型密封件的新型 Santoprene 热塑性硫化胶（TPVs）。
两家公司通过采用杜邦公司设计的硅基添加剂，代替传统有机助滑添加剂，开发出新一代 Santoprene 热塑
性硫化胶 (TPVs)。
这不仅改善了与乙烯丙烯二烯单体（EDPM）橡胶基材的粘合性能，而且摩擦系数（COF）较低，使门窗更
易开关。
全新系列 Santoprene TPV B260 产品，还具有更优异的流动性、耐磨性和紫外线光稳定性。
(R-03)
·4· 第 45 卷 第 15 期
