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理论与研究 刘湘慧·扫描电子显微镜 / 能谱仪分析钢帘线与橡胶之间的黏合机理
Zn 和 Fe 的化学分布，观察到橡胶残留带与 Cu/Zn 空
隙区的位置相匹配。进一步的研究表明，相邻的 Cu/
Zn 带形成了一个山谷宏观结构，这对橡胶残留物机械
连锁起着重要的作用。这些结果为钢丝帘线与橡胶材
料之间的黏合研究提供了一个新的视角，同时也为新
图 2 钢帘线与橡胶黏合的模型图 型钢丝帘线的设计提供了潜在的见解。
化学分布信息。基于 SEM/EDX 结果，在钢丝表面发
参考文献 ：
现黄铜带取向，这可能是拉拔过程引起的。钢丝和橡
Yusheng Chen and Jeremy L. Schlarb. Steel Cord–Rubber
胶复合材料中抽出或剥离钢丝帘线时，钢丝帘线表面 Adhesion with SEM/EDX [J]. TIRE SCIENCE AND
也有类似的橡胶残留带。用 EDX 比较元素 C、Cu、 TECHNOLOGY，2018，46(1):27~37.
Analysis of the bonding mechanism between steel cord and rubber by
scanning electron microscope/energy spectrometer
Liu Xianghui 1,2
(1.Jiangsu Xingda Steel Tyre Cord Co.LTD., Taizhou 225721, Jiangsu, China;
2.Jiangsu Key Laboratory of Structural and Functional Metal Composites, Taizhou 225721, Jiangsu, China)
Abstract: Brass-plated steel cords are widely used as reinforcing materials for rubber composites. The
adhesion of steel cords and rubber is critical throughout the life of the steel cord/rubber. Therefore, the
bonding mechanism is a focus of the rubber industry for decades. Various modern analytical instruments, such
as X-ray spectrometers and mass spectrometers, have been applied to the study of the bonding interface. In
this paper, the surface morphology and bonding mechanism of steel cords were studied by scanning electron
microscopy/energy dispersive X-ray spectroscopy (SEM/EDX). Based on the results of these morphological
tests, it was observed that the rubber residual zone was mainly located in the Cu/Zn void region. Further
research indicates that the macrostructure of the adhesive layer leads to the interlocking mechanism of
rubber residues.
Key words: brass plating; SEM; EDX; microstructure; macrostructure; adhesion of rubber and steel cord;
brass band; chemical mapping
（R-05)
15 万 t 氯丁橡胶项目落户包头
150 000 tons of neoprene project settled in Baotou
2018 年，内蒙古包头市九原区政府与晋胶高新技术（上海）有限公司，签署 15 万 t 丁橡胶项目合作协议。
九原区区委书记高勇、晋胶公司董事长孙静宇，代表双方在协议上签字。
据了解，15 万 t 丁橡胶项目由晋胶公司投资建设。
这个项目总投资 51 亿元，分三期建设，其中一期投资 20 亿元，建设年产 3 万 t 丁橡胶生产线。
签约仪式前，与会人员参观了晋胶氯丁橡胶及胶乳产品，并进行座谈交流。
资料显示，晋胶公司成立于 2012 年，是一家高新技术企业。
氯丁橡胶广泛应用于各种橡胶制品及胶黏剂产品。
摘编自 “ 轮胎世界网 ”
(R-03)
2018 第 44 卷 ·19·
年
