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橡塑技术与装备                                          CHINA RUBBER/PLASTICS  TECHNOLOGY  AND EQUIPMENT

                 Epoxy Resin[J]. Materials Today: Proceedings, 2020, 27: 2   Layered Antimony Hydroxide and Its Flame Retardancy in
                 269-2 272.                                        Thermoplastic Polyurethane[J]. Journal of Thermal Analysis
             [63]  Sanchez-olivares  G,  Sanchez-solis A,  Calderas  F,  et  al.   and Calorimetry, 2020, 142(1): 425-435.
                 Flame Retardant High Density Polyethylene Optimized By   [71]  Z ha n J,  Wa ng L , Hong N, e t  a l . Fl a m e -re t a rda nt  a nd
                 On-line Ultrasound Extrusion[J]. Polymer Degradation and   Anti-dripping Properties of Intumescent Flame-retardant
                 Stability, 2013, 98(11): 2 153-2 160.             Polylactide with Different Synergists[J]. Null, 2014, 53(4):
             [64]  Hof fendahl  C,  Fontaine  G,  Duquesne  S,  et  al.  The   387-394.
                 Combination of Aluminum Trihydroxide (ath) and Melamine   [72]  Doğan   M,   Bayramlı   E.   Syner gistic   Ef fect   of   Boron
                 Borate (mb) as Fire Retardant Additives for Elastomeric   Containing Substances on Flame Retardancy and  Thermal
                 Ethylene  Vinyl Acetate (eva)[J]. Polymer Degradation and   Stability of Clay Containing Intumescent Polypropylene
                 Stability, 2015, 115: 77-88.                      Nanoclay Composites[J]. Polymers for  Advanced
             [65]  Zhang  T, Liu  W,  Wang M, et al. Synergistic Effect of   Technologies, 2011, 22(12): 1 628-1 632.
                 an  Aromatic Boronic  Acid Derivative and Magnesium   [73]  Tai Q, Yuen RK, Yang  W, et al. Iron-montmorillonite and
                 Hydroxide on the Flame Retardancy of Epoxy Resin[J].   Zinc Borate as Synergistic Agents in Flame-retardant Glass
                 Polymer Degradation and Stability, 2016, 130: 257-263.  Fiber Reinforced Polyamide 6 Composites in Combination
             [66]  Carpentier F, Bourbigot S, Le bras M, et al. Charring   with Melamine Polyphosphate[J]. Composites Part  A:
                 of Fire Retarded Ethylene  Vinyl  Acetate Copolymer-   Applied Science and Manufacturing, 2012, 43(3): 415-422.
                 Magnesium Hydroxide/zinc Borate Formulations[J]. Polymer   [74]  Lim  WP, Mariatti M, Chow  W, et al.  Thermal and Flame
                 Degradation and Stability, 2000, 69(1): 83-92.    Properties  of Calcium Borate and  Intumescent Ammonium
             [67]  Dogan  M,  Dogan  SD,  Savas  LA,  et  al.  Flame  Retardant   Polyphosphate in Epoxy/glass Fiber Composites[J]. Journal
                 Effect of Boron Compounds in Polymeric Materials[J].   of Fire Sciences, 2012, 30(5): 428-436.
                 Composites Part B: Engineering, 2021, 222: 109 088.  [75]  Wang N,  Liu  H,  Zhang J,  et  al.  Synergistic  Effect  of
             [68]  Wu Z, Shu  W, Hu Y. Synergist Flame Retarding Effect of   Graphene Oxide and Boron-nitrogen Structure on Flame
                 Ultrafine Zinc Borate on Ldpe/ifr System[J]. Journal of   Retardancy of Natural Rubber/ifr Composites[J]. Arabian
                 Applied Polymer Science, 2007, 103(6): 3 667-3 674.  Journal of Chemistry, 2020, 13(8): 6 274-6 284.
             [69]  Zhang R, Huang H, Yang W, et al. Effect of Zinc Borate on   [76]  Wu Q, Guo J, Fei B, et al. Synthesis of a Novel Polyhydroxy
                 the Fire and  Thermal Degradation Behaviors of a Poly(3-  Triazine-based Charring Agent and Its Effects on Improving
                 hydroxybutyrate-co-4-hydroxybutyrate)-containing   the Flame Retardancy of Polypropylene with Ammonium
                 Intumescent Flame Retardant[J]. Journal of Applied Polymer   Polyphosphate and Zinc Borate[J]. Polymer Degradation and
                 Science, 2012, 125(5): 3 946-3 955.               Stability, 2020, 175: 109 123.
             [70]  Qian  Y, Qiao P, Li L, et al. Preparation of Pillared


               Research progress and prospect of boron-containing flame retardant
                                                 polymer materials

                     Han Dequan, Tian Huhu, Guo Liying, Zhou Xiaodong, Lu Tingting, Yu Xiaoli, Cao Hongzhang *

               (Baotou Rare Earth Research Institute, State Key Laboratory of Research and Comprehensive Utilization of
                            Rare Earth Resources in Bayan Obo, Baotou 014030, Inner Mongolia, China)

                 Abstract: In recent years, due to environmental and health concerns, many researchers have been
             focusing on finding halogen-free flame retardant solutions that are as effective as halogenated flame
             retardant solutions. This strategy is a major impetus for academic work in the field of flame retardants.
             Boron compounds are potential flame retardant additives in polymer materials due to their low toxicity,
             molecular diversity and various flame retardant action modes. They have been used alone or as adjuvants
             in combination with expansion systems, phosphorus-, halogen-, nitrogen- and carbon-containing additives.
             This article comprehensively describes the flame retardant effects of boron compounds in biocomposites,
             thermoplastics, elastomers, and thermosets, as well as studies on synergistic effects with other flame retardant
             additives. Finally, the challenges of the application of boron-containing flame retardants in polymer materials
             are emphasized, and the future research progress in this field was expected.
                 Key words: boron-containing compound; polymer material; flame retardant; synergistic effect
                                                                                                         (R-03)

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