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综述与专论                                             周成飞·氮化硼 / 聚合物复合材料的制备及应用研究进展


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                0.028  S cm 。而 Oh 等  [21]  则采用氮化硼纳米片和磺                Dielectric Performance[J].Materials, 2017,10(7):741~746.
                                                                  [8]   Chen  Y,Gao X,Wang J,et al.Properties and application
                化聚醚醚酮(SPEEK)制备了燃料电池用聚合物电解
                                                                      of   polyimide‐based   compos ites   by   blending   surface
                质膜(图 5)。研究表明,这种聚合物电解质膜具有良                             functionalized boron nitride nanoplates[J].Journal of
                好的质子质子转运特性。                                           Applied Polymer Science, 2015,132(16):67~71.
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                                                                      thermal  properties  of  hexagonal  boron  nitride  filled  high‐
                                                                      performance polymer nanocomposites[J].Journal of Applied
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                                                                  [10]  Wang J,Li H,Liu Z,et al.Noncovalent functionalization of
                                                                      boron nitride and its effect on the thermal conductivity of
                                                                      polycarbonate composites[J].Journal of Applied Polymer
                   图 5 氮化硼 /SPEEK 复合聚电解质膜的制备过程                        Science, 2017, 134(25):83~89.
                                                                  [11]  Terao  T,Bando  Y,Mitome M,et al.Thermal Conductivity
                    另外,Siddiqui 等   [22]  还采用所制备的二维六角六                Improvement of Polymer Films by Catechin-Modified
                角氮化硼 (hNB)/ 聚乙烯醇 (PVOH) 纳米复合材料(图                      Boron Nitride Nanotubes[J].Journal of Physical Chemistry
                                                                      C, 2009,113(31): 13 605~13 609.
                6),研究过作为柔性电阻开关器件的记忆效应。结果
                                                                  [12]  Jiang Y,Shi  X,Feng Y,et  al.Enhanced  thermal  conductivity
                表明,这种复合材料在电阻开关方面有良好的应用前                               and ideal dielectric properties of epoxy composites
                景。                                                    containing polymer modified hexagonal boron nitride[J].
                                                                      Composites Part A: Applied Science and Manufacturing,
                                                                      2018,107(4):657~664.
                                                                  [13]  Zhi C,Bando Y,Terao T,et al. Boron Nanotube–Polymer
                                                                      Composites: Towards Thermoconductive,Electrically Insulating
                                                                      Polymeric Composites with Boron Nitride  Nanotubes  as
                                                                      Fillers[J].Advanced Functional Materials, 2010,19(12):1
                图 6 氮化硼 / 聚乙烯醇(PVOH)纳米复合材料的制备                         857~1 862.
                                   过程图示
                                                                  [14]  Zhang  Y,Choi J R,Park S J.Enhancing the heat and load
                                                                      transfer efficiency by optimizing the interface of hexagonal
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                2019     第   45 卷                                                                      ·19·
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