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橡塑技术与装备(塑料)                            CHINA RUBBER/PLASTICS  TECHNOLOGY  AND EQUIPMENT (PLASTICS)

                 of graphene oxide/polyimide hybrid membrane for   Power Sources, 2015,299(12):255~264.
                 CO 2  separationby surface modification  of  graphene   [19]  Zhang P,Zhao J,Zhang K,et al.Fluorographene/polyimide
                 oxide using polyet hyl ene glycol[J].Appl ied Surfac e   composite films: Mechanical, electrical, hydrophobic,
                 Science,2018,440(5):1 063~1 072.                  thermal  and  low dielectric properties[J].Composites Part A:
             [15]  Shukla G,Pandey R P,Shahi  V K.Temperature resistant   Applied Science and Manufacturing, 2016,84(5):428~434.
                 phosphorylated graphene oxide-sulphonated polyimide   [20]  Wa ng  J  Y,Ya ng  S  Y,Hua ng  Y  L ,et   al .Pre pa ra t i on  a nd
                 composite cation exchange membrane for water desalination   properties of graphene oxide/polyimide composite films
                 with improved performance[J].Journal of Membrane   with low dielectric constant and ultrahigh strength via
                 Science, 2016,520(12):972~982.                    in situpolymerization[J].Journal of Materials Chemistry,
             [16]  Kowsari E,Zare A,Ansari  V.Phosphoric acid-doped ionic   2011,21(35):13 569~13 575.
                 liquid-functionalized graphene oxide/sulfonated polyimide   [21]  Chen  X,Huang  H,Shu  X,et  al.Preparation  and  properties  of
                 composites as proton exchange membrane[J].International   a novel graphene fluoroxide/polyimide nanocomposite film
                 Journal of Hydrogen Energy, 2015,40(10):13 964~13 978.  with a low dielectric constant[J].Rsc Advances, 2017,7(4):
             [17]  Huang  Y,Li  K,Liu  J,et  al.Three-dimensional  graphene/  1 956~1 965.
                 polyimide composite-derived flexible high-performance   [22]  Ma  L,Niu  H,Cai  J,et  al.Photoelectrochemical  and
                 organic cathode for rechargeable lithium and sodium   electrochromic properties of polyimide/graphene oxide
                 batteries[J ].J ournal of Materials  Chemistry  A ,   composites[J].Carbon, 2014,67(1):488~499.
                 2017,5(6):47~56.                              [23]  Iroh  J,Okafor  P.Fabrication  of  porous  graphene/polyimide
             [18]  Cao L,Kong L,Zhang X,et al.Novel sulfonated polyimide/  composites using leachable polyacrylic resin for enhanced
                 zwitterionic polymer-functionalized graphene oxide hybrid   electrochemical and energy storage capabilities[J].Journal
                 membranes for vanadium redox flow battery[J].Journal of   of Materials Chemistry A, 2015,3(33):17 230~17 240.
                   Progress in preparation and application of graphene-polyimide
                                                  nanocomposites


                                                      Zhou Chengfei
                           (Beijing Radiation Center for Research and Application, Beijing 100015, China)
                 Abstract: In this paper, the preparation methods of graphene-polyimide nanocomposites are introduced.
             The applications of graphene-polyimide nanocomposites in sensors, separation membranes, ion proton
             exchange membranes, battery materials, low dielectric materials and electronic materials are reviewed.
                 Key words: graphene; polyimide; nanocomposites; in-situ polymerization; solution blending
                                                                                                         (R-03)


                                            东丽开发新型纳米层薄膜
                                           Toray developed New nano-layer thin films

                 日本东丽实业宣布,成功开发出了一种具有高紫外线 (UV) 阻挡性的透明薄款纳米薄膜,可遮挡 99.99% 的
             紫外线。
                 该公司将在现有的 Picasus 系列纳米薄膜中新增一个产品等级,命名为 Picasus UV。东丽将在 OLED 显示器
             应用领域推广该材料以延长设备使用寿命,并预计将在 2020 年得到全面采用。新材料上市后的 3 年内,使其年
             销售额达到数十亿日元水平。
                 据了解,东丽开发的 Picasus  UV 薄膜由两种只有纳米级厚度的聚酯层组成,成百上千层纳米级薄层叠放在
             一起形成了薄膜。紫外线在这些多层膜中反复反射和吸收,能够有效地被阻挡。由于传统的薄膜不能简单地通过
             添加紫外线吸收剂来实现这一功能,东丽新开发的新产品显著提高了紫外线遮挡性。
                 OLED 显示器容易受到潮湿、受热和紫外线的影响。在波长接近 400  nm 的紫外线下环境下暴露,OLED 显
             示器性能会退化。而东丽开发的 Picasus UV 薄膜可以实现遮挡几乎全部 410 nm 以下的紫外光,同时仍允许 92%

             的可见光通过该材料。东丽已经开始向潜在客户销售 Picasus  UV,预计这类新材料将用于 OLED 智能手机的覆
             盖膜和触摸传感器,并用作圆偏振器的偏光保护膜。
                                                                                       摘编自“中国化工报”
                                                                                                         (R-03)
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