Page 35 - 2018-12
P. 35

研究与开发                                                                   豆鹏飞·聚乙烯增韧改性研究


                    2006,(3):13~17.                                   ultraviolet  irradiation  and  its  compatibilization[J].  Polymer
                [3]   刘生鹏,张苗 . 聚乙烯改性研究进展 [J].  武汉工程大学学报,              Bulletin,2006,57(4):595~602.
                    2010,32(3):31~36.                             [10]  孙聚华,邹向阳,金永峰,等 . 氯磺化聚乙烯的合成 [J]. 弹性
                [4]   李孝三,王德禧 . 聚烯烃的化学结构改性 [J].中国塑料,                  体,2008,18(2):34~37.
                    1990,4(4):17~25.                              [11]  王诚,郝荣山 .  共混改性聚乙烯管材材质的研究 [J].  塑料科
                [5]   申屠宝卿,赵黎,等 . 聚乙烯的表面光接枝改性研究进展 [J].                技,1999,(4):5~7.
                    高分子通报,2001,(4):24~38.                         [12]  林群球,刘浩,卢红 . LDPE/LLDPE 共混改性矿用管的研制
                [6]   刘君,李金钟,王曼,等 . 聚乙烯表面紫外光接枝 MPC 及其                 [J]. 塑料科技,2001,(4):20~21.
                    性能研究 [J]. 润滑和密封,2008,(4):42~50.               [13]  汤亚明 .  LLDPE 与 HDPE 共混改性的研究 [J].  塑料包装,
                [7]   吴晓云,覃伟中 . 我国聚乙烯专用树脂应用情况分析 [J]. 石油               1999,9(3):5~8.
                    化工技术经济,2002,21(6):17~20.                      [14]  王新鹏,张军 .  LDPE/POE 共混物的结品行为和力学性能 [J]
                [8]   李星,刘东辉,杨明,等 . 辐射交联聚乙烯薄膜的研究 [J]. 现               .合成树脂及塑料,2009,26(1):10~14.
                    代塑料加工应用,2002,14(2):5~8.                       [15]  赵枫,杨琪,杨云波 .  PP/POE/PE 共混改性的研究 [J].  石油
                [9]   Wu Shi Shan,Chen Zheng Nian,Ma Qing Qing,eta1.   技术与应用,2002,20(4):239~240.
                    Studies on linear tow-density polyethylene functionalized by


                              Study on toughening modification of polyethylene

                                                          Dou Pengfei

                                     (Changqing Oilfield Company, Yulin 718100, Shaanxi, China)
                    Abstract: Polyethylene (PE), as one of the top five synthetic resins, is also China's largest synthetic resin
                with the largest production capacity and the largest import volume. With its good processing performance,
                mechanical properties, chemical corrosion resistance, low temperature resistance, and the advantages of
                wide source and low price, it has been widely used in the fields of film, packaging, pipe, sheet, fiber and so
                on. Because of its good chemical corrosion resistance, low temperature resistance, water permeability and
                low price, it has a great application prospect in building waterproof materials. However, there are many
                kinds of polyethylene, and the performance and price of polyethylene of different kinds are quite different.
                Single polyethylene is difficult to meet the performance requirements of building waterproof materials. The
                main purpose of this study is to improve the toughness, strength, cohesiveness and low temperature flexural
                properties of polyethylene by blending modification of PE/POE and PE/EVA, so as to achieve the national
                standard of waterproof sheet for construction and make the product have certain economic benefits. In this
                paper, the effects of the ratio of different grades of polyethylene in the blending modification system of HDPE/
                LLDPE/POE and HDPE/LLDPE/EVA and the influence of the mixing ratio of POE (or EVA) on the properties of
                the blends were discussed. The tensile properties, tear strength, watertightness, low temperature bending, hot
                air aging, alkali solution aging and other properties of the materials after blending modification were tested,
                to find out the relationship between material ratio and performance. Furthermore, the product formula with
                all indexes reaching or even exceeding the national standard has been screened out and achieved good
                results initially.
                    Key words: polyethylene; polyolefin elastomers; polyethylene vinyl acetate
                                                                                                            (R-03)














                2018     第   44 卷                                                                      ·19·
                      年
   30   31   32   33   34   35   36   37   38   39   40