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橡塑技术与装备 CHINA RUBBER/PLASTICS TECHNOLOGY AND EQUIPMENT

Technology . 2021. [J] . Iranian Polymer Journal . 2020 (10).
[12] Mohammad Alimardani .The correlation of tear deviation [21] 王永军 . 不同类型偶联剂对热解炭黑的表面改性及应用研究
and resistance with the bound rubber content in rubber-silica [J]. 特种橡胶制品 , 2021,42(01):13-16.
composites [J] . Polymer Testing . 2020. [22] Wise P L.Structure-microwave property relations of Ca and
[13] Q ingxu Zhang. Influence of hydroxyl-terminated Sr titanates, Journal of the European Ceramic Society[J].
polybutadiene liquid on rheology of fumed silica filled cis- 2001, 21:2 629–2 632.
polybutadiene rubber [J] . Polymer . 2019 (C). [23] 邵辉 . 硅烷偶联剂对 CABS 玻璃 /α-Al 2 O 3 复合料流延性能的
[14] Lijian Xia.Silica nanoparticles reinforced natural rubber 影响 [J]. 电子元件与材料，2016(5):77-80.
latex composites: The effects of silica dimension and [24] Yunxi ang Hu. Mi crowa ve die le ct ric propert ie s of
polydispersity on performance [J]. Journal of Applied PTFE/Ca TiO3 polym erceramic composites. Ceramics
Polymer Science . 2019 (18) . International[J]. 2011, 37(2): 1 609-1 613.
[15] Ahn, Kim. Effect of the functional group of silanes on the [25] Yuan Ying.Influence of SiO 2 Addition on Properties of
modification of silica surface and the physical properties PTFE/TiO 2 Microwave Composites[J]. Journal of Electronic
of solution styrene-butadiene rubber/silica composites[J] Materials, 2017.
Composite Interfaces, 2019, 26(7). [26] Koulouridis.Polymer–Ceramic Composites for Microwave
[16] A. Ansarifar.Optimising the chemical bonding between Applications: Fabrication and Performance Assessment[J].
silanised silica nanofiller and natural rubber and assessing IEEE Transactions on Microwave Theory & Techniques,
its effects on the properties of the rubber[J] International 2006, 54(12):4 202-4 208.
Journal of Adhesion and Adhesives, 2005, 26(6). [27] Murali K P. Effects of silane coatings in aqueous and non-
[17] Khalil Ahmed. The effect of silica on the properties of aqueous media on the properties of magnesia filled PTFE
marble sludge filled hybrid natural rubber composites[J] laminates[J]. Materials Chemistry and Physics, 2010,
Journal of King Saud University-Science, 2013, 25(4). 122(2-3):317-320.
[18] 李秋红 . 一种轮胎用高分散防老化纳米填料的制备方 [28] 金霞 . 低吸水率和低介电损耗 PTFE/SiO 2 复合材料制备 [J].
法 .CN202111281119.7. 工程塑料应用，2020,48(07):33-37.
[19] 甄博鸣 . 一种非硅烷聚合物偶联剂、制备方法及可硫化橡胶组 [29] 王雪明 . 硅烷偶联剂在金属预处理及有机涂层中的应用研究
合物 . CN 112011062A. [D] 山东大学硕士学位论文，2005,27-34.
[20] Yuan Tang.Application of carboxylated ethylene/vinyl [30] 柴颂刚 . 硅烷偶联剂处理球形二氧化硅 [C]. 中国颗粒学会第
acetate copolymer-modified nanosilica in tire tread rubber 七届学术年会暨海峡两岸颗粒技术研讨会，2010(8):126-127.

Research progress in surface modification technology of inorganic
fillers for rubber composite materials

Deng Changyou
(Zhejiang Ypoo Health Technology Co. LTD., Jinhua 321000, Zhejiang, China)

Abstract: Rubber, as an important raw material for tires, its application occasions determine that rubber
composite materials must have good mechanical properties. The use of inorganic fillers as reinforcing materials
to improve mechanical properties has become a development trend in recent years. The current research
hotspot in the field of rubber composite materials is the combination and use of various fillers. However, most
inorganic fillers have strong self polymerization or poor dispersibility due to their high polarity, making them less
compatible with rubber substrates. The surface modification of inorganic fillers through coupling agents can
promote their uniform dispersion in the rubber matrix, thereby endowing tire rubber materials with excellent
mechanical and dynamic mechanical properties. By reviewing relevant literature in the past decade, classify
and extract technical details of interdisciplinary research on surface modification of inorganic fillers. Conduct
a horizontal comparison of the research results of surface modification technologies for different material
systems, summarize the advantages and disadvantages, and conduct in-depth analysis. Finally, through cross
comparison, summarize the current nano level inorganic filler surface modification technologies, solve the
problems in research, and discuss solutions and future research directions.
Key words: rubber; reinforced materials; coupling agent; mechanical properties; dynamic mechanical
performance
(R-03)

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